Increasing Safety in Chemical Waste Water Treatment Plant

Waste water treatment and location of the measurement.

Purified Terephthalic Acid (PTA) is the preferred raw material for the most common plastic products of daily life. The PTA production process generates various waste water streams which are high in organic content.

Purification of Process Waste Water

In the waste water treatment plant, the water treatment starts with aeration. The last step is an anaerobic bio reactor where the treatment is done in a controlled atmosphere. Micro organisms purify the water and produce biogas. Biogas roughly consists of 60 % methane and 40 % Carbon dioxide. This biogas is compressed and used as a fuel to reduce the net energy supply.

Although production or intrusion of oxygen into the reactors or pipes is highly unlikely, safety systems are installed. In case air enters unexpectedly into the process this first may result in a non-supporting atmosphere for the microbes and in the worst case the gas mixture may lead to an explosion.

Safety Guaranteed Using Siemens LDS 6

To ensure that oxygen never exceeds the maximum accepted concentration, the customer chose an in-situ measurement with the Siemens Laser Diode Spectrometer LDS 6. LDS 6 performs a continuous monitoring of the oxygen concentration in the biogas produced.

Measurement path and the
two LDS 6 sensor heads.

The response of the system is in three levels:

1. In case the oxygen level exceeds 5 % an alarm is triggered.
2. The threshold of 7 % causes an automatic nitrogen injection and the closure of a valve preventing the gas mixture from entering into the compressor.
3. When the limit of 9 % is exceeded, this automatically shuts down the compressor.

The in-situ measurement leads to a fast and reliable measurement.

The stability and availability of the LDS 6 system is ensured by the integrated reference cell which provides a lifetime calibration. To be absolutely on the safe side, the customer operates a weekly safety check which involves opening a valve that allows a controlled air intake into the LDS 6 sensor heads. As the sensor heads are physically separated from the process by process windows, no oxygen may enter into the process. The reaction of the system shows in any of these tests once more the reliability of the measurement method used.

For more information about this application, or for any analytical instrument requirement, contact Ives Equipment by calling (877) 768-1600 or visiting https://www.ivesequipment.com.

Reprinted with permission from Siemens Case Study.

Remote Sensing of Gases Directly in the Process

Electric Power Plant

Industrial operations, whether for direct process control or emissions compliance monitoring, have a need for accurate, reliable measurement of specific gas concentrations within a flowing medium. Tunable diode laser spectroscopy, packaged for industrial use, provides a number of substantially positive attributes.

• Rapid measurement.
• Can be focused on a specific component of interest.
• Multi-channel operation provides analysis of several components.
• In situ installation can provide direct measurements within a stack, pipe, or duct without sample handling or conditioning.
• Can measure NH3, HF, HCl, H2O, CO, CO2.
• Internal reference cell provides long term stability.
• Some models have continuous automatic calibration.

Siemens manufactures a line of tunable diode laser gas analyzers for industrial applications. In the company's own words, here is a basic description of how it works.

As a tunable diode laser-based technology this in-situ device enables high-performance measurements. The sensors (transmitter and receiver) are meant to be mounted directly on the process with no need of sampling systems. Laser light is sent from the transmitter, passing through the process gas, arriving at the detector on the receiver side. The measurements are carried out on-line with a very short response time permitting fast and effective cost-savings in process control. The laser characteristics allow single-line spectroscopy free of interferences. Since the band width of the laser light is extremely narrow, only the gas component of interest will interact with it. Other process influences, such as dust and temperature, are easily eliminated due to the excellent inherent compensation capabilities of this technique.

There is application assistance and more detailed information available from knowledgeable sales engineers in all localities. Combine your process mastery with their product application resources to meet the challenges posed by modern industrial process operation.

Sitrans Tunable Diode Laser Gas Analyzer from Ives Equipment